Fiche de CATTEY Hélène

Since 2005 (Thematic mobility): Structural determination by X-ray diffraction of single crystals

1999-2005: Electrosynthesis and organometallic electrochemistry

Since 1999: Assistant Professor, Institute of Molecular Chemistry of the University of Burgundy (ICMUB) CNRS UMR6302, Dijon, France

1998-1999: Post-doctoral researcher (Center for Research on Materials at High Temperatures, UPR4212, Orléans in partnership with ALCATEL

1997-1998: Assistant Lecturer (University of Franche-Comté)

1994-1997: Ph. D., University of Franche-Comté, Molecular Chemistry and Electrochemistry Laboratory under the direction of Pierre Audebert (Allocataire de recherche MESR) partnership with the Laboratory of Molecular Electrochemistry, Paris VII (P. Hapiot), the Condensed Matter Chemistry Laboratory, Paris VI (C. Sanchez) and the National Office for Aerospace Studies and Research (ONERA) Chatillon (A.J. Attias)

1993-1994: DEA de Physical Chemistry (University of Franche-Comté)

1991-1992: Bachelor of Science of Chemistry (Polytechnic d’Huddersfield)

My research activity, focuses on structural determination but also on the analysis of the reactivity of complexes and their mode of coordination. Within the ICMUB (Institute of Molecular Chemistry of the University of Burgundy), I am involved in several projects (ANR, Region, PHC) led by SEM (Molecular Synthesis, Environment and Materials) department members of this unit (before the OCS and EMMD teams). I also develop national and international scientific collaborations (see list of publications).

137 publications (April 2025) : 31 publications Q1, 47 publi Q2, 32 publi Q3, 27 publi Q4

Selection of 10 recent articles most representative of my research

– Normand, A. T.; Cattey, H.; Penouilh, M.-J.; Bonnin, Q.; Fleurat-Lessard, P.; Pichon, C.; Sutter, J.-P. An Ambiphilic Phosphide with Three Different Coordination Modes to Group 7–10 Metals. Inorg. Chem. 2025, 64 (8) 4168–4182. https://doi.org/10.1021/acs.inorgchem.5c00201

– Edlová, T.; Rybáček, J.; Cattey, H.; Vacek, J.; Bednárová, L.; Le Gendre, P.; Normand, A. T.; Stará, I. G.; Starý, I. Stereocontrolled Synthesis of Chiral Helicene‐Indenido Ansa ‐ and Half‐Sandwich Metal Complexes and Their Use in Catalysis. Angew Chem Int Ed 2025, 64 (1), e202414698. https://doi.org/10.1002/anie.202414698

– Sire, C.; Tsivery, A.; Sabbadin, H.; Cattey, H.; Penouilh, M.-J.; Fleurat-Lessard, P.; Hierso, J.-C.; Roger, J. Rhodacycles Activity in P-Directed Rhodium-Catalyzed Synthesis of π-Extended Aromatic Fluoranthenyl Phosphines. Eur. J. Inorg. Chem. 2025, e202400721. https://doi.org/10.1002/ejic.202400721

–  Nguyen, T. A.; Daiann Sosa Carrizo, E.; Cattey, H.; Fleurat-Lessard, P.; Roger, J.; Hierso, J. C. Tetranuclear Dicationic Aurophilic Gold(I) Catalysts in Enyne Cycloisomerization: Cooperativity for a Dramatic Shift in Selectivity. Chem Eur J 2022, 28 (27), e202200769. https://doi.org/10.1002/chem.202200769

– Gelin, L.; Sabbadin, H.; Cattey, H.; Fleurat‐Lessard, P.; Hierso, J.; Roger, J. Direct Palladium‐Catalyzed C5‐Arylation of 1,3,4‐Oxadiazoles with Aryl Chlorides Promoted by Bis(Di‐ Iso Propylphosphino) Ferrocene. Eur J Org Chem 2024, 27 (21), e202400212. https://doi.org/10.1002/ejoc.202400212

– Daher, A.; Bousfiha, A.; Tolbatov, I.; Mboyi, C. D.; Cattey, H.; Roisnel, T.; Fleurat-Lessard, P.; Hissler, M.; Hierso, J. C.; Bouit, P. A.; Roger, J. Tetrazo[1,2-b]Indazoles: Straightforward Access to Nitrogen-Rich Polyaromatics from s-Tetrazines. Angew Chem Int Ed Engl 2023, 62 (13), e202300571. https://doi.org/10.1002/anie.202300571

–  Mboyi, C. D.; Vivier, D.; Daher, A.; Fleurat-Lessard, P.; Cattey, H.; Devillers, C. H.; Bernhard, C.; Denat, F.; Roger, J.; Hierso, J. C. Bridge-Clamp Bis(Tetrazine)s with [N]8 Pi-Stacking Interactions and Azido-s-Aryl Tetrazines: Two Classes of Doubly Clickable Tetrazines. Angew Chem Int Ed Engl 2020, 59 (3), 1149– 1154. https://doi.org/10.1002/anie.201911947

– Cattey, H.; Penouilh, M.-J.; Bonin, Q.; Plasseraud, L. Isolation and Characterization of [n-Bu₂Sn(OH₂)(Phen)(OSO₂CF₃)](O₃SCF₃) (Phen = 1,10-Phenanthroline): The Missing Link. Journal of Organometallic Chemistry 2025, 123511. https://doi.org/10.1016/j.jorganchem.2025.123511

– Bousfiha, A.; Fournier, S.; Cattey, H.; Fleurat-Lessard, P.; Devillers, C. H.; Lucas, D.; Hierso, J.-C.; Roger, J. Synthesis and Reactivity of s -Aryltetrazines Palladacycles Toward a Direct o -Aryl C–H Bond Halogenation Achieved by Electrocatalysis. Organometallics 2024, 43 (8), 807–816. https://doi.org/10.1021/acs.organomet.3c00497

– Bousfiha, A.; Amiri, N.; Akhssas, F.; Berthelot, M.; Echaubard, J.; Pirrotta, M.; Cattey, H.; Fleurat-Lessard, P.; Roger, J.; Devillers, C. H. Synthesis of Meso ,β-Fused Thiazinamine-Porphyrins via Oxidative C–N Fusion of Pyrimidinyl-Substituted Porphyrins. Org. Lett. 2023, 25 (44), 7979–7983. https://doi.org/10.1021/acs.orglett.3c03062

Liste complète de publications

Liste complète

Enseignements

Approx 200h in IUT, License and Master: TD, TP and CM

– IUT: Biological Engineering (30%)

General and organic chemistry ; Analytical techniques

– Bachelor’s degree in Chemistry (15%)

General Chemistry; electrochemistry ; Interdisciplinarity (PIX)

– 1^st year of Master (30%)

Analytical Chemistry; Measurements and uncertainties; Technological risks (radiation protection)

– 2^nd year of Master (15%)

Analytical Chemistry; Sampling and preliminary treatments

– Tutoring, follow-up of internships in initial training and work-study, VAE (10%)

Research

• Since 2023: Referent « Parity, non-discriminatory treatment and prevention of violence » of ICMUB
• Since 2006: Person Competent in Radiation protection (PCR) for the ICMUB Diffractometers:

Single crystals analysis (co-manager): Diffractometer Bruker Nonius Kappa APEX II (CDD / Sealed tube Mo) and Bruker D8 Venture (Photon III C7 / microfocus IµS 3.0 Ag / sealed tube Cu high brilliance microfocus); Powder analysis: Diffractometer Theta – 2 Theta Panalytical Empyrean

• Since 2003: Elected member of the ICMUB Institute Council

Education

• Since 2022: Co-referent Handicap of the UFR Sciences et Techniques
• Since 2023: Co-teaching manager of the first year of Master « Chemical Control and Analysis » of the University of Burgundy
• 2009-2018: Head of the first year of Master « Chemical Control and Analysis » of the University of Burgundy

Administrative

• 2019-2023: Member of the National University Council (CNU) section 32