Fiche de PLASSERAUD Laurent

PLASSERAUD Laurent
Adresse : ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
Bât. MIRANDE - Aile B - Bureau B120
9 Avenue Alain Savary
21000 Dijon – France
Tél : (+33) 380 399 160
E-mail : laurent.plasseraud@u-bourgogne.fr
Equipe : CapCom
Fonction : Chargé de recherche CNRS
Tags : Chimie de Coordination, Chimie Verte, Polymères, Chimie Structurale
ORCID : 0000-0002-7870-1881
  • Carrière
  • Projet
  • Publications
  • Communications
  • Enseignement
Carrière

Laurent Plasseraud est Chargé de Recherche CNRS en poste à l’Université de Bourgogne (Dijon-France).
Ses principaux résultats concernent l’identification de structures originales de complexes de métaux de transition et du bloc principal, en relation avec la durabilité, la catalyse homogène, la chimie supramoléculaire et les matériaux moléculaires.
Depuis son entrée au CNRS (2001), il a consacré ses activités de recherche à des projets en chimie durable s’employant notamment à valoriser le dioxyde de carbone en tant que synthon C1. Plus récemment, il s’est orienté vers la transformation de molécules biosourcées pour accéder à des composés chimiques et à des matériaux à plus fortes valeurs ajoutées.

Projet

Activités de recherche relevant de la section 14 du comité national du CNRS :

  • La valorisation du dioxyde de carbone pour la synthèse directe de carbonates organiques,
  • La chimie de coordination des métaux du bloc principal,
  • La chimie des 2-carboxylates d’imidazolium – application en organo-catalyse,
  • La valorisation de molécules bio-sourcées,
  • L’ingénierie cristalline.

Interdisciplinarité :

  • La compréhension des processus de bio-minéralisation carbonatée chez les métazoaires –collaboration avec le Dr. F. Marin du laboratoire Biogéosciences de Dijon, UMR CNRS 6282,
  • Le développement de matériaux composites bio-sourcés innovants destinés à des applications structurales – collaboration avec le Dr. V. Placet du laboratoire FEMTO-ST de Besançon, UMR CNRS 6174.
    Actions financées : BQR PRES Bourgogne Franche-Comté (2014-2016),
    Co-encadrements de 2 thèses, ANR MRSEI (2015-2017),
    Projet européen BBI-2017 – Horizon 2020 (2017-2021).
Publications

Selection de publications :

– Organotin(IV) Complexes Containing Sn-O-Se Moieties: A Structural Inventory, L Plasseraud, Synthesis 2018, 50, 3653–3661.

– (n-Bu2Sn)2O(CO3): An active, robust and recyclable organotin(IV) for the direct synthesis of linear organic carbonates from carbon dioxide and alcohols, SR Sanapureddy, L Plasseraud, Applied Organometallic Chemistry 2017, 31, 2335–2342.

– Diglycidylether of iso-eugenol: A suitable lignin-derived synthon for epoxy thermoset applications, C François, S Pourchet, G Boni, S Fontaine, Y Gaillard, V Placet, M V Galkin, A Orebom, J Samec, L Plasseraud, RSC Advances 2016, 6, 68732–68738.

– Undecylenic acid: A tunable bio-based synthon for material applications, S. Bigot, M. Daghrir, A. Mhanna, G. Boni, S. Pourchet, L. Lecamp, L. Plasseraud, European Polymer Journal 2016, 74, 26-37.

– Organo-catalyzed synthesis of aliphatic polycarbonates in solvent-free conditions, PU Naik, K Refes, C-H Brachais, G Boni, J-P Couvercelle, M Picquet, L Plasseraud, Polymer Chemistry 2012, 3, 1475–1480.

– Tin-based Mesoporous Silica for the Conversion of CO2 into Dimethyl Carbonate, D Ballivet-Tkatchenko, F Bernard, F Demoisson, L Plasseraud, SR Sanapureddy, ChemSusChem 2011, 4, 1316–1322.

– Di-n-butyltin Oxide as a Chemical Carbon Dioxide Capturer, L Plasseraud, D Ballivet-Tkatchenko, H Cattey, S Chambrey, R Ligabue, P Richard, R Willem, M Biesemans, Journal of Organometallic Chemistry 2010, 695, 1618–1626.

– Imidazolium-2-Carboxylate as an Efficient, Expeditious and Eco-Friendly Organocatalyst for Glycerol Carbonate Synthesis, PU Naik, L Petitjean, K Refes, M Picquet, L Plasseraud, Advanced Synthesis & Catalysis 2009, 351, 1753–1756.

– Direct Synthesis of Dimethyl Carbonate with Supercritical Carbon Dioxide: Characterization of a Key Organotin Oxide Intermediate, D Ballivet-Tkatchenko, S Chambrey, R Keiski, R Ligabue, L Plasseraud, P Richard, H Turunen, Catalysis Today 2006, 115, 80–87.

– A meso-Helical Coordination Polymer from Achiral Dinuclear [Cu2(H3CCN)2(-pydz)3][PF6]2 and 1,3-Bis(diphenylphosphanyl)propane — Synthesis and Crystal Structure of ∞ {[Cu(-pydz)2][PF6]}, L Plasseraud, H Maid, F Hampel, RW Saalfrank, Chemistry: a European Journal 2001, 7, 4007–4011.

– [(6-p-PriC6H4Me)4Ru4Mo4O16]: An Amphiphilic Organoruthenium Oxomolybdenum Cluster Presenting a Unique Framework Geometry, G Süss-Fink, L Plasseraud, V Ferrand, H Stoeckli-Evans, Chemical Communication 1997, 1657–1658.

– Unprecedented Mode of Bonding for Olefins on Bimetallic Complexes: An Agostic Interaction of a sp2 C-H Bond with a Ruthenium Centre in Addition to a  Bond to a Rhenium Centre, Z He, L Plasseraud, I Moldes, F Dahan, D Neibecker, M Etienne, R. Mathieu, Angewandte Chemie International English Edition 1995, 8, 916–917.

 

Liste complète de publications :

Alioune Wane, Antoine Blaise Kama, Mouhamadou Birame Diop, Libasse Diop, Laurent Plasseraud, et al.. Propane-1,3-diammonium molybdate. IUCrData, 2019, 4 (4), ⟨10.1107/S2414314619005005⟩. ⟨hal-02122722⟩
Jordan Vigier, Camille François, Sylvie Pourchet, Gilles Boni, Laurent Plasseraud, et al.. Crystal structure of the diglycidyl ether of eugenol. Acta crystallographica Section E : Crystallographic communications [2015-..], 2017, 73 (5), pp.694 - 697. ⟨10.1107/S2056989017005370⟩. ⟨hal-01543417⟩
Mouhamadou Birame Diop, Libasse Diop, Laurent Plasseraud, Hélène Cattey. Crystal structure of 2-methyl-1 H -imidazol-3-ium hydrogen oxalate dihydrate. Acta crystallographica Section E : Crystallographic communications [2015-..], 2016, 72 (8), pp.1113-1115. ⟨10.1107/s2056989016011038⟩. ⟨hal-02122858⟩
Mouhamadou Birame Diop, Libasse Diop, Laurent Plasseraud, Thierry Maris. Crystal structure of bis(2-methyl-1 H -imidazol-3-ium) dihydroxidobis(oxalato-κ 2 O 1 , O 2 )stannate(IV) monohydrate. Acta crystallographica Section E : Crystallographic communications [2015-..], 2016, 72 (3), pp.355 - 357. ⟨10.1107/S2056989016002061⟩. ⟨hal-01400193⟩
Assane Toure, Cheikh Abdoul Khadir Diop, Libasse Diop, Laurent Plasseraud, Hélène Cattey. Ethylammonium hydrogen oxalate–oxalic acid (2/1). IUCrData, 2019, 4 (5), ⟨10.1107/S2414314619006357⟩. ⟨hal-02187663⟩
Waly Diallo, Libasse Diop, Cheikh Abdoul Khadir Diop, Hélène Cattey, Laurent Plasseraud. Synthesis, spectroscopic study, and crystal structure of a new organotin(IV) selenate derivative. Main Group Metal Chemistry, 2018, 41 (5-6), pp.183-188. ⟨10.1515/mgmc-2018-0029⟩. ⟨hal-02122764⟩
Hélène Cattey, Laurent Plasseraud. Organotin(IV) trifluoromethanesulfonate chemistry: isolation and characterization of novel 1,10-phenanthroline-based derivatives. Comptes Rendus. Chimie, 2024, 27 (S1), pp.1 - 18. ⟨10.5802/crchim.260⟩. ⟨hal-04686844⟩
Laurent Plasseraud. Glycerol as Ligand in Metal Complexes—A Structural Review. Crystals, 2024, 14 (3), pp.217. ⟨10.3390/cryst14030217⟩. ⟨hal-04586311⟩
Camille Lutet-Toti, Marie da Silva Feliciano, Nelly Debrosse, Jérôme Thomas, Laurent Plasseraud, et al.. Diverting the use of hand-operated tablet press machines to bioassays: a novel protocol to test ‘waste’ insoluble shell matrices.. Methods and Protocols, 2024, 7 (2), pp.30. ⟨10.3390/mps7020030⟩. ⟨hal-04567920⟩
Konstantinos Karakostis, Isabelle Zanella-Cléon, Françoise Immel, Nathalie Guichard, Philippe Dru, et al.. A minimal molecular toolkit for mineral deposition? Biochemistry and proteomics of the test matrix of adult specimens of the sea urchin Paracentrotus lividus.. Journal of Proteomics, 2016, 136, pp.133-144. ⟨10.1016/j.jprot.2016.01.001⟩. ⟨hal-01283937⟩
Communications

Main Group Metal Chemistry in Burgundy Sauce, 1st French Main Group Metal Chemistry Symposium, Rennes, France (2018).
Catalytic Transesterification of Organic Carbonates with Bio-based Building Blocks, 9 th Workshop on Fats and Oils as Renewable Feedstock for the Chemical Industry, Karlsruhe, Allemagne (2017).
High-pressure NMR spectroscopy: An in situ tool to study tin-catalyzed synthesis of organic carbonates from carbon dioxide and alcohols, 15th International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead, ICCOC-15, Pardubice, République Tchèque (2016).
Photopolymerizable Synthons From Fatty acids and Glycerol Derivatives, Biomass Conversion: Green Chemistry & Innovative Processes  A Nordic-French conference, Paris, France (2016).
Novel Alkali-Metal Hydrido-tris(pyrazolyl)borate Complexes, 6 th EuChemS Conference on Nitrogen Ligands, Beaune, France (2015).
Organotin(IV)-Oxo Clusters Chemistry: Unprecedented Polynuclear Frameworks, Journées de la Division Chimie de Coordination de la Société Française de Chimie, Strasbourg, France (2012).
Organotin(IV) Chemistry Made in Dijon, 2 nd Czech-French Vltava meeting of Chemistry, Pardubice, République Tchèque (2011).
Dimethyl carbonate: direct synthesis from carbon dioxide and application in transesterification reaction, 42th Symposium on Catalysis, Prague, République Tchèque (2010).

Enseignement

Master 2 “Molecular Chemistry and Metals for Health and Sustainable Development (MMHD)”, module “Chemicals and Materials from Renewable Resources” (depuis 2017).