Sheet of BAYARDON Jérôme

BAYARDON Jérôme
Address : ICMUB Institut de Chimie Moléculaire de l'Université de Bourgogne
Bât. MIRANDE - Aile B - Bureau B-222
9 Avenue Alain Savary
21000 Dijon – France
Phone number : (+33) 380 396 102
E-mail : jerome.bayardon@ube.fr
Team : CapCoM
Function : Associate Professor
Tags : Catalysis, Heterochemistry, Synthetic chemistry
ORCID : 0000-0003-2165-1315
  • Career
  • Project
  • Publications
  • Communications
  • Training and skills
Career

After the obtention of my PhD in organic and organometallic chemistry as well as in asymmetric catalysis at the University of Lyon in 2004 under the supervision of Pr. Denis Sinou, I worked for one year as lecture-assistant in the same University. Then I worked for one year as a postdoctoral research fellow on the development of a new media for asymmetric catalysis in the group of Professor Börner at the Leibniz Institüt für Organische Katalyse in Rostock (Germany). In 2006, I joined the team of Pr. Sylvain Jugé as an assistant professor at the Université of Bourgogne-Franche Comté where I obtained my HDR in 2016.

ORCID : 0000-0003-2165-1315

Project

My current interests are the synthesis of (P-chirogenic) phosphorus compounds for (asymmetric) catalysis with transition metals and organocatalysis.

Publications

34 articles, 5 patents (3 with international extension), 3 sealed folds (envelope Soleau), 2 book chapters

Main publications:
1) Efficient sythesis of quaternary and P-stereogenic phosphonium triflates
E. Rémond, A. Tessier, F. R. Leroux, J. Bayardon, S. Jugé, Org. Lett201012, 1568-1571
2) Stereoselective synthesis of o-bromo (or iodo)aryl P-chirogenic phosphines based on aryne chemistry
J. Bayardon, H. Laureano, V. Diemer, M. Dutartre, U. Das, Y. Rousselin, J. -C. Henry, F. Colobert, F. R. Leroux, S. Jugé, J. Org. Chem201277, 5759-5769
3) Stereoselective synthesis of unsaturated and functionalized L-NHBoc amino acids, using Wittig reaction under mild phase transfer conditions
E. Rémond, J. Bayardon, M. -J. Ondel-Eymin, S. Jugé, J. Org. Chem201277, 7579-7587
4) o-(Hydroxylalkyl)phenyl P-Chirogenic phosphines as functional chiral Lewis bases
E. Rémond, J. Bayardon, S. Takisawa, Y. Rousselin, H. Sasai, S. Jugé, Org. Lett201315, 1870-1873
5) P-chirogenic organocatalysts: application to the aza-Morita-Baylis-Hillman (aza-MBH) reaction of ketimines
S. Takizawa, E. Rémond, F. A. Arteaga, Y. Yoshida, V. Sridharan, J. Bayardon, S. Jugé, H. Sasai, Chem. Commun.201348, 8392-8394
6) Efficient synthesis of (P-chirogenic) o-boronated phosphines from sec-phosphine boranes
J. Bayardon, J. Bernard, E. Rémond, Y. Rousselin, R. Malacea-Kabbara, S. Juge, Org. Lett201517, 1216-1219
7) Modular P-chirogenic phosphine-sulfide-ligands: clear evidence for both electronic effect and P-chirality driving enantioselectivity in Pd-catalyzed allylations
J. Bayardon, M. Maronnat, A. Langlois, Y. Rousselin, P. D. Harvey, S. Juge, Organometallics2015, 34, 4340-4358
8) Designing P-chirogenic 1,2-diphosphinobenzenes at both P6centers using P(III)-phosphinites
J. Bayardon, Y. Rousselin, S. Jugé, Org. Lett201618, 2930-2933
9) Applications and setreoselective syntheses of P-chirogenic phosphorus compounds
M. Dutartre, J. Bayardon, S. Jugé, Chem. Soc. Rev201645, 5771-5794

Full list

Valentin Vaillant-Coindard, Jérôme Bayardon, Yoann Rousselin, Raluca Malacea-Kabbara, Jean-Thomas Pouzens, et al.. Prolinol‐derived phenoxy‐amidine titanium complexes in asymmetric silylcyanation of aldehydes. European Journal of Inorganic Chemistry, 2024, ⟨10.1002/ejic.202400405⟩. ⟨hal-04730433⟩
Jérôme Bayardon, Chen Qian, Raluca Malacea-Kabbara, Yoann Rousselin, Sylvain Jugé. Enantioselective Synthesis of P-chirogenic 1,2,3-triazolobenzophospholes. The Journal of organic chemistry, 2024. ⟨hal-04730220⟩
Amira Sayed Khan, Aziz Hichami, Babar Murtaza, Marie-Laure Louillat-Habermeyer, Christophe Ramseyer, et al.. Novel Fat Taste Receptor Agonists Curtail Progressive Weight Gain in Obese Male Mice. Cellular and Molecular Gastroenterology and Hepatology, 2023, 15 (3), pp.633-663. ⟨10.1016/j.jcmgh.2022.11.003⟩. ⟨hal-04226771⟩
Floriane Mangin, Naim Khan, Sylvain Jugé, Jérôme Bayardon, Amira Khan. Oleic acid derivatives, pharmaceutical composition or food composition comprising said oleic acid derivatives, and their uses. France, Patent n° : WO2019228994. 2019. ⟨hal-04269673⟩
Floriane Mangin, Naim Khan, Sylvain Jugé, Aziz Hichami, Jérôme Bayardon, et al.. Pharmaceutical or food compositions including oleic acid derivatives modulating CD36 and/or GPR120 receptors for treatment of obesity linked to excessive intake of dietary fatty acids. France, Patent n° : EP3574899. 2019. ⟨hal-04269654⟩
Valentin Vaillant-Coindard, Florian Chotard, Benjamin Théron, Cédric Balan, Jérôme Bayardon, et al.. Bis(salicylamidine) Ligands (FAlen): A Variant of Salen with “à la Carte” Denticity. Inorganic Chemistry, 2023, 62 (19), pp.7342-7352. ⟨10.1021/acs.inorgchem.3c00493⟩. ⟨hal-04225835⟩
Benjamin Théron, Valentin Vaillant-Coindard, Cédric Balan, Yoann Rousselin, Jérôme Bayardon, et al.. Al and Zn phenoxy-amidine complexes for lactide ROP catalysis. Dalton Transactions, 2023, 52 (23), pp.7854-7868. ⟨10.1039/D3DT01216F⟩. ⟨hal-04225864⟩
Valentin Vaillant-Coindard, Benjamin Théron, Gaël Printz, Florian Chotard, Cédric Balan, et al.. Phenoxy-Amidine Ligands: Toward Lactic Acid-Tolerant Catalysts for Lactide Ring-Opening Polymerization. Organometallics, 2022, 41 (21), pp.2920-2932. ⟨10.1021/acs.organomet.2c00343⟩. ⟨hal-03875645⟩
Benjamin Rousselle, Aurélie Massot, Malorie Privat, Lucile Dondaine, Audrey Trommenschlager, et al.. Conception and Evaluation of Fluorescent Phosphine‐Gold Complexes: From Synthesis to in vivo Investigations. ChemMedChem, 2022, 17 (11), pp.e202100773. ⟨10.1002/cmdc.202100773⟩. ⟨hal-03806346⟩
Shinobu Takizawa, Emmanuelle Rémond, Fernando Arteaga Arteaga, Yasushi Yoshida, Vellaisamy Sridharan, et al.. P-chirogenic organocatalysts: application to the aza-Morita–Baylis–Hillman (aza-MBH) reaction of ketimines. Chemical Communications, 2013, 49 (75), pp.8392-8394. ⟨10.1039/C3CC44549F⟩. ⟨hal-03572274⟩
Communications

21 oral communications and 39 poster in 39 national and international congresses.

Training and skills

Training

– First and second year of bachelor’s degree : general and organic chemistry
– Professional bachelor’s degree in Control-Process-Quality for the Pharmaceutical, Cosmetological and health Industries: Co-lead, organic chemistry, spectroscopic and chromatographic methods

 

Skills

Organic chemistry, Phosphorus chemistry, asymmetric synthesis and catalysis.